December 23, 2016

Surface Chemistry

 Surface Chemistry

Adsorption - Physisorption and chemisorption and their characteristics, factors affecting adsorption of gases on solids - Freundlich and Langmuir adsorption isotherms, adsorption from solutions.
Catalysis - Homogeneous and heterogeneous, activity and selectivity of solid catalysts, enzyme catalysis and its mechanism.
Colloidal state - distinction among true solutions, colloids and suspensions, classification of colloids - lyophilic, lyophobic; multi molecular, macromolecular and associated colloids (micelles), preparation and properties of colloids - Tyndall effect, Brownian movement, electrophoresis, dialysis, coagulation and flocculation; Emulsions and their characteristics.

Solutions

 Solutions

Different methods for expressing concentration of solution - molality, molarity, mole fraction, percentage (by volume and mass both), vapour pressure of solutions and Raoult’s Law - Ideal and non-ideal solutions, vapour pressure - composition, plots for ideal and non-ideal solutions; Colligative properties of dilute solutions - relative lowering of vapour pressure, depression of freezing point, elevation of boiling point and osmotic pressure; Determination of molecular mass using colligative properties; Abnormal value of molar mass, van’t Hoff factor and its significance

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Importance of  Core Revision Points
Core Revision Points are important because if you remember them strongly, many more points related to them will come out of your memory and help you to answer question and problems. Read them many times and make sure you remember them very strongly.


Sections in the Chapter
Different methods for expressing concentration of solution - molality, molarity, mole fraction, percentage (by volume and mass both),

vapour pressure of solutions and Raoult’s Law - Ideal and non-ideal solutions, vapour pressure - composition, plots for ideal and non-ideal solutions;
Colligative properties of dilute solutions -
  1. relative lowering of vapour pressure, 
  1. depression of freezing point, 
  1. elevation of boiling point and 
  1. osmotic pressure; 
Determination of molecular mass using colligative properties; 
Electrolytic solutions- Abnormal value of molar mass,
van’t Hoff factor and its significance
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👌Solutions Practice Sets: Link

👌MCQ :Link
👌CBSE Question :Link
👌NEET MCQ :Link
👌WBCHSE Question :Link


d and f Block Elements

Transition Elements

General introduction, electronic configuration, occurrence and characteristics, general trends in properties of the first row transition elements - physical properties, ionization enthalpy, oxidation states, atomic radii, colour, catalytic behaviour, magnetic properties, complex formation, interstitial compounds, alloy formation; Preparation, properties and uses of K2Cr2O7 and KMnO4.

Inner Transition Elements

Lanthanoids - Electronic configuration, oxidation states, chemical reactivity and lanthanoid contraction.
Actinoids - Electronic configuration and oxidation states.




Transition Elements Practice Sets: Link 

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